Spaniard posted a picture on his official Twitter account from Monday's 1-0 win with the caption "the last trip"
33-year-old was part of the Spain sides which lifted the 2010 World Cup, Euro 2008 and Euro 2012 titles
Madrid captain is set to overtake Iker Casillas and become his country's most capped player with his 168th appearances
33-year-old captain is set to match his former Real Madrid and Spain team mate Casillas' record of 167 caps in Gijon
37-year-old suffered what his club, Porto called an "acute myocardial infarction" in training