As the report was published, international monitors from the Organization for Security and Cooperation in Europe (OSCE) mission in the former Soviet state said one of their teams had been shot at by a man in uniform.
While the OSCE described Wednesday's incident as "isolated", it highlights continuing high tensions in eastern Ukraine, where government forces and pro-Russian rebels are fighting a drawn-out battle for territory.
The Kremlin denies Western and Ukrainian accusations that it is backing the separatist rebels with troops and military equipment but diplomatic relations have plunged to a low not seen since the Cold War over the seven-month conflict.
US Vice President Joe Biden is due in Kiev later Thursday ahead of Friday's anniversary of the start of the Maidan protests against the former pro-Kremlin regime which eventually led to the conflict in the east.
The report from the UN Human Rights Monitoring Mission in Ukraine put the number of dead at 957 from September 5, when the ceasefire was signed, to November 18.
"The list of victims keeps growing. Civilians, including women, children, minorities and a range of vulnerable individuals and groups continue to suffer the consequences of the political stalemate in Ukraine," UN High Commissioner for Human Rights Zeid Ra'ad Al Hussein said in a statement.
Counting the 298 people who died in the downing of Malaysia Airlines flight MH17 over Ukraine in July, the overall toll since mid-April, when fighting started, stood at 4,317 deaths as of Tuesday.
The report also detailed grave human rights abuses on both sides.
One Ukrainian soldier said his right arm, bearing a "Glory to Ukraine" tattoo, had been chopped off with an axe by rebels.
A separatist detained by Ukrainian forces in Donetsk said he had been suffocated with a plastic bag and repeatedly beaten.
It also highlighted the huge volume of people registered as displaced within Ukraine by the conflict, with the number soaring from 275,489 in mid-September to 466,829 as of Wednesday.
Giving details of the shooting incident, the OSCE said a uniformed man on the back of a truck fired two shots in the direction of their vehicles near the government-held town of Mariinka, some 15 kilometres (nine miles) west of the rebel stronghold of Donetsk, on Wednesday.
"The bullets struck about two metres from the second OSCE vehicle," the statement added.
The OSCE said it was the first "direct" shot deliberately fired at observers during the mission.
The incident followed another Tuesday when a warning shot was fired towards an OSCE vehicle from a Ukrainian checkpoint near the frontline hotspot of Debaltseve.
The OSCE has nearly 300 observers working in Ukraine to monitor the ceasefire which has stopped fighting around much of the conflict zone but failed to halt bombardments at strategic flashpoints.
A 58-year-old female nurse was killed and one other civilian wounded in shelling close to the rebel-stronghold of Lugansk, the region's pro-Kiev governor said.
Rebels said one of their fighters was killed and three injured in Donetsk over the past day.
Six Ukrainian soldiers were wounded in the past 24 hours, Ukrainian security spokesperson Andriy Lysenko said.
Biden, the latest high-profile Western politician to visit Kiev in the hope of shoring up the ceasefire, is due to meet President Petro Poroshenko and Prime Minister Arseniy Yatsenyuk on Friday.
The US vice president is set to discuss "Russia's ongoing violations of the September 5 Minsk agreement," a statement from his office said, referring to the truce deal.
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This is worse than Indo-Pak ceasefire at the LoC.