Standing in the courtyard of the Elysee under slow and steady rain, Macron and his wife Brigitte welcomed some 70 monarchs, heads of state and prime ministers.
All will travel together in buses to the Arc de Triomphe for the ceremony. US President Donald Trump is expected to join them there.
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The commemoration is the centrepiece of global tributes to honour the 10 million soldiers killed during the 1914-18 war and mark the moment the Armistice, signed in northeastern France, came into effect at 11 am on Nov. 11, 1918.
World leaders, including Trump, German Chancellor Angela Merkel and Russian President Vladimir Putin, will be seated under a glass canopy at the foot of the Arc de Triomphe, built by Emperor Napoleon in 1806, for the ceremony.
Macron is expected to speak and light a flame in honour of an unknown soldier who was killed in the war and whose remains are buried with others under the triumphal arch.
Afterwards, Macron will host a lunch for the dignitaries at the Elysee. In a rare public display of emotion by the leaders of two world powers, Macron and Merkel held hands on Saturday during a poignant ceremony in the Compiegne Forest, north of Paris, where French and German delegations signed the Armistice that ended the war.
Testimonies written by soldiers on Nov. 11, 1918, as the ceasefire took hold, will be read at Sunday's event by high school students in French, English and German. The conflict was one of the bloodiest in history, reshaping Europe's politics and demographics.
Peace, however, was short-lived and two decades later Nazi Germany invaded its neighbours. On Sunday afternoon, Macron will host the inaugural Paris Peace Forum, which seeks to promote a multilateral approach to security and governance and ultimately avoid the errors that led to the outbreak of World War One.
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Merkel said in a statement the forum showed that "today there is a will, and I say this on behalf of Germany with full conviction, to do everything to bring a more peaceful order to the world, even though we know we still have much work to do."
Trump, who champions a nationalist 'America first' policy, will not attend the forum. The US leader has said he will also not hold a bilateral meeting with Putin in Paris. Trump and Putin are expected to have formal talks later this month when both attend a G-20
summit in Buenos Aires.
Should the two leaders chat briefly during Sunday's events, their body language will be closely scrutinised. Special Counsel Robert Mueller is probing alleged Russian interference in the 2016 US election and any possible collusion with Trump's campaign.
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